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Nato Science Series C: Ser.: Energetics of Organometallic Species by José A. Martinho Simões (2012, Trade Paperback)

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These papers reflect a variety of research interests, and discuss results obtained with several techniques. The historical perspective is followed by a discussion of a very actual issue: the trends of stepwise bond dissociation enthalpies.

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Product Information

An overview of modern organometallic thermochemistry, made by some of the most active scientists in the area, is offered in this book. The contents correspond to the seventeen lectures delivered at the NATO ASI Energetics of Organometallic Species (Curia, Portugal, September 1991), plus three other invited contributions from participants of that summer school. These papers reflect a variety of research interests, and discuss results obtained with several techniques. It is therefore considered appropriate to add a few preliminary words, attempting to bring some unity out of that diversity. In the first three chapters, results obtained by classical calorimetric methods are described. Modern organometallic thermochemistry started in Manchester, with Henry Skinner, and his pioneering work is briefly surveyed in the first chapter. The historical perspective is followed by a discussion of a very actual issue: the trends of stepwise bond dissociation enthalpies. Geoff Pilcher, another Manchester thermochemist, makes, in chapter 2, a comprehensive and authoritative survey of problems found in the most classical of thermochemical techniques - combustion calorimetr- applied to organometallic compounds. Finally, results from another classical technique, reaction-solution calorimetry, are reviewed in the third chapter, by Tobin Marks and coworkers. More than anybody else, Tobin Marks has used thermochemical values to define synthetic strategies for organometallic compounds, thus indicating an application of thermochemical data of which too little use has been made so far.

Product Identifiers

Publisher
Springer Netherlands
ISBN-10
9401050880
ISBN-13
9789401050883
eBay Product ID (ePID)
175722165

Product Key Features

Author
José A. Martinho Simões
Publication Name
Energetics of Organometallic Species
Format
Trade Paperback
Language
English
Series
NATO Science Series C: Ser.
Publication Year
2012
Type
Textbook
Number of Pages
Xii, 442 Pages

Dimensions

Item Length
9.4in
Item Width
6.3in
Item Weight
25.7 Oz

Additional Product Features

Series Volume Number
367
Number of Volumes
1 Vol.
Lc Classification Number
Qd410-412.5
Table of Content
Foreword. 1. Historical Perspective of Organometallic Thermochemistry; H.A. Skinner. 2. Combustion Calorimetry of Organometallic Compounds; G. Pilcher. 3. Organo-f-Element Thermochemistry, Implications for Reactivity and Bonding from Metal-Ligand Bonding Energetics; M.A. Giardello, W.A. King, S.P. Nolan, M. Porchia, C. Sishta, T.J. Marks. 4. The Role of Bond Energies in Hydrocarbon Activation by Transition Metal Centers; W.D. Jones, R.M. Chin, L. Dong, S.B. Duckett, E.T. Hessell. 5. Rh-C Bond Dissociation Enthalpies for Organometallic Derivatives of Rhodium Porphyrins; B.B. Wayland. 6. Solution Thermochemistry of Organometallic Compounds Using Photoacoustic Calorimetry: Enthalpies of Ligand Exchange, Metal-Ligand Bonds, and Metal-Solvent Interactions; T.J. Burkey. 7. Electrochemistry of some Organic and Organometallic Radicals and their Application in Thermochemical Cycles; D.D.M. Wayner. 8. Derivative Cyclic Voltammetry: Applications in the Investigation of the Energetics of Organometallic Electrode Reactions; M. Tilset. 9. The Use of Calorimetric and Sublimation Techniques to Study Bond Properties in Organometallic Compounds; A.S. Carson. 10. Estimating Enthalpies of Sublimation of Hydrocarbons; J.S. Chickos, D.G. Hesse, J.F. Liebman. 11. Derivation of Thermodynamic Quantities from Kinetic Measurements in Gas Phase Silane Chemistry; R. Walsh. 12. Bond Enthalpy Transferability -- Is It Achievable? J.A. Connor. 13. Estimates of Thermochemical Data for Organometallic Compounds; J.A. Martinho Simões. 14. Bonding and Solvation Energetics for Organometallic Gas-PhaseMolecules and Ions: Experimental Approaches and Thermodynamic Insights; D.E. Richardson. 15. Gas-Phase Acidities of Transition-Metal Carbonyl and Trifluorophosphine Hydrides; A.E. Stevens Miller, T.M. Miller. 16. Bond Strengths in Transition Metal Carbonyl Anions; L.S. Sunderlin, R.R. Squires. 17. Fundamental Gas Phase Studies of the Mechanism and Thermochemistry of Organometallic Reactions; J.L. Beauchamp, P.A.M. van Koppen. 18. Guided Ion Beam Studies of the Energetics of Organometallic Species; P.B. Armentrout, D.E. Clemmer. 19. A Guide to Density Functional Theory and its Practical Applications to the Energetics of Organometallic Species; T. Ziegler. 20. Theoretical Models for Organometallic Reactions; M.R.A. Blomberg, P.E.M. Siegbahn, M. Svensson, J. Wennerberg. List of Posters and Contributed Oral Presentations. Subject Index.
Copyright Date
1992
Target Audience
Scholarly & Professional
Topic
Chemistry / Organic, Chemistry / Industrial & Technical, Chemistry / Inorganic
Illustrated
Yes
Genre
Science

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Picture 1 of 1

Nato Science Series C: Ser.: Energetics of Organometallic Species by José A. Martinho Simões (2012, Trade Paperback)

About this product

Product Information

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All listings for this product

item 1 Energetics of Organometallic Species by Jos? A. Martinho Sim?es (English) Paperb

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