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Moldes Quirales Derivados Del Norborneno by Aljarilla Jiménez Ana Isabel (2012, Trade Paperback)

About this product

About this product

Product Information

El trabajo que se presenta en esta Tesis Doctoral consiste en el empleo de dos tipos de moldes quirales que han sido utilizados para la preparación de compuestos tetrahidrofuránicos, pirrolidínicos e indolizidínicos. El primer tipo de molde quiral son derivados del 7-oxabiciclo[2.2.1]hepteno para los cuales se ha puesto a punto un método sintético basado en la reacción Diels-Alder entre el carbonato de vinileno y furano, seguida de separación de los cicloaductos formados, hidrólisis y desimetrización enzimática. Por otro lado se empleo el 2-aza-3-oxo-norborneno, accesible comercialmente. Los sistemas 7-oxabicíclicos se emplearon como productos de partida para la preparación de oxetanos tricíclicos, conocidos herbicidas, de derivados tetrahidrofuránicos tetrasustituidos y de furanopironas, análogos de compuestos lactónicos de contrastada actividad biológica. Los compuestos azabicíclicos permitieron obtener pirrolidinonas ópticamente puras, compuestos bien documentados como auxiliares quirales. Asimismo la secuencia tandem ROM-CM-RCM sobre este tipo de compuestos ha dado lugar a la preparación derivados pirrolizidínicos, sin precedentes en la literatura.

Product Identifiers

Publisher
Editorial Academica Espanola
ISBN-10
3659009709
ISBN-13
9783659009709
eBay Product ID (ePID)
150525225

Product Key Features

Book Title
Moldes Quirales Derivados Del Norborneno
Author
Aljarilla Jiménez ANA Isabel
Format
Trade Paperback
Language
English
Topic
Chemistry / Organic
Publication Year
2012
Genre
Science
Number of Pages
456 Pages

Dimensions

Item Length
9in
Item Height
1in
Item Width
6in
Item Weight
23.6 Oz

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